Pre-heat oven to 350 degrees Fahrenheit. Grease a half sheet cake pan (18 x 13 inches or similar) and set aside
Whisk or sift together the flour, cocoa powder, baking powder, baking soda, and salt. Stir in the instant coffee granules.
In the bowl of a stand mixer fitter with the paddle attachment, mix together the sugar and oil until smooth until some of the sugar begins to dissolve, about 2 minutes.
With the mixer on medium, add the eggs, one at a time. Add the vanilla. Stop the mixer and scrape down the sides of the bowl.
Add half of the flour mixture and mix on low speed to combine. Continue mixing while streaming in the buttermilk. Mix until smooth. Add the remaining flour mixture and mix until combined.
Slowly stream in the hot water and mix until the batter is smooth.
Pour the batter into the prepared pan and bake for 30 to 35 minutes, or until a toothpick inserted into the center of the cakes comes out clean or with a few moist crumbs.